Quantum Inequalities in Quantum Mechanics

نویسندگان

  • Simon P. Eveson
  • Christopher J. Fewster
  • Rainer Verch
چکیده

We study a phenomenon occuring in various areas of quantum physics, in which an observable density (such as an energy density) which is classically pointwise nonnegative may assume arbitrarily negative expectation values after quantisation, even though the spatially integrated density remains nonnegative. Two prominent examples which have previously been studied are the energy density (in quantum field theory) and the probability flux of rightwardsmoving particles (in quantum mechanics). However, in the quantum field context, it has been shown that the magnitude and space-time extension of negative energy densities are not arbitrary, but restricted by relations which have come to be known as ‘quantum inequalities’. In the present work, we explore the extent to which such quantum inequalities hold for typical quantum mechanical systems. We derive quantum inequalities of two types. The first are ‘kinematical’ quantum inequalities where spatially averaged densities are shown to be bounded below. Specifically, we obtain such kinematical quantum inequalities for the current density in one spatial dimension (imposing constraints on the backflow phenomenon) and for the densities arising in Weyl–Wigner quantization. The latter quantum inequalities are direct consequences of sharp G̊arding inequalities. The second type are ‘dynamical’ quantum inequalities where one obtains bounds from below on temporally averaged densities. We derive such quantum inequalities in the case of the energy density in general quantum mechanical systems having suitable decay properties on the negative spectral axis of the total energy. Furthermore, we obtain explicit numerical values for the quantum inequalities on the onedimensional current density, using various spatial averaging weight functions. We also improve the numerical value of the related ‘backflow constant’ previously investigated by Bracken and Melloy. In many cases our numerical results are controlled by rigorous error estimates.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Quantum Mechanics and the Mechanism of Sexual Reproduction

There are many claims that quantum mechanics plays a key role in the origin and/or operation of biological organisms. The mechanism of the meiosis, mitosis and gametes life cycle from the view-point of quantum for human has been represented. The quantum gates have been used to simulate these processes for the first time. The reason of several hundred sperms has been explained in the male too

متن کامل

Quantum Mechanics and the Mechanism of Sexual Reproduction

There are many claims that quantum mechanics plays a key role in the origin and/or operation of biological organisms. The mechanism of the meiosis, mitosis and gametes life cycle from the view-point of quantum for human has been represented. The quantum gates have been used to simulate these processes for the first time. The reason of several hundred sperms has been explained in the male too

متن کامل

Structure-Activity Relationship of Imidazobenzodiazepines, an AM1 Semi-Empirical Quantum Mechanics Study

Conformations and electronic properties of a series of imidazobenzodiazepines are investigated by AM1 semi-empirical quantum mechanics method. It is shown that substitution of Cl in position 7 instead of 8, changes the geometry of the seven membered lactam ring; this may put the N5 nitrogen in a better positon to act as a hydrogen bond acceptor, and the phenyl ring in position 6 is probably...

متن کامل

Transannular Interaction in N-Aryl-5-Azocanones, A Semiempirical Quantum Mechanics and UV Spectroscopy Studies

The ability of the present semiempirical quantum mechanics methods are surveyed for reproducing the transannular interaction in the bifunctional N-phenyl-5-azocanones. The AM1 method is the best with the order of reliability being Am1, PM3, MNDO and MINDO/3. AM1 calculations were then carried out for quantification of transannular interaction. The n(o) ionization potential has be...

متن کامل

Quantum Mechanics-Molecular Mechanics Model Study of some Antibiotics and Vitamins in Gas Phases: Investigation of Energy and NMR Chemical Shift

The combination of Quantum Mechanics (QM) and Molecular Mechanics (MM) methods hasbecome alternative tool for many applications that pure QM and MM could not be suitable.The QM/MM method has been used for different type of problems, for example: structuralbiology, surface phenomena, and liquid phase. In this paper we have performed these methods forsome antibiotics and vitamins and then we comp...

متن کامل

Quantum mechanics investigation of acid dissociation constant of carboxylic acids in aqueous solution

According to the Bronsted definition, any compound which has a hydrogen atom is an acid, since itmay be lost as a proton. A thermodynamical cycle is proposed to calculate absolute pKa values forBronsted acids in aqueous solution. The equilibrium of dissociation of a Bronsted acid depends onthe interaction of the acid and its conjugate base with solvent molecules. There fore the pKa valuedepends...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2005